CAS 9003-49-0 Butyl acrylate resin - Materials / Alfa Chemistry

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Butyl acrylate resin

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Catalog Number

ACM9003490

Product Name

Butyl acrylate resin

Structure

CAS

9003-49-0

Category

Polymers

Synonyms

butyl acrylate resin;POLY(N-BUTYL ACRYLATE);POLY(BUTYL ACRYLATE);N-BUTYL ACRYLATE RESIN;2-Propenoicacid,butylester,homopolymer;Acrylicacid,butylester,homopolymer;n-butylacrylateresin(40%intoluene;ButylacrylateresinintoluenemedMWt

Description

Butyl acrylate appears as a clear colorless liquid with a sharp characteristic odor. Very slightly soluble in water and somewhat less dense than water. Hence forms surface slick on water. Flash point 105°F. Density 7.5 lb / gal. Used for making paints, coatings, caulks, sealants, adhesives.;Liquid;COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.;Clear, colorless liquid with a strong, fruity odor.;Clear, colorless liquid with a strong, fruity odor. [Note: Highly reactive; may contain an inhibitor to prevent spontaneous polymerization.]

IUPAC Name

butyl prop-2-enoate

Molecular Weight

128.17g/mol

Molecular Formula

CH2=CHCOOC4H9;C7H12O2;C7H12O2

Canonical SMILES

CCCCOC(=O)C=C

InChI

InChI=1S/C7H12O2/c1-3-5-6-9-7(8)4-2/h4H,2-3,5-6H2,1H3

InChI Key

CQEYYJKEWSMYFG-UHFFFAOYSA-N

Boiling Point

295 to 298 °F at 760 mm Hg (NTP, 1992);145.0 °C;145 °C;145-149 °C;293°F;293°F

Melting Point

-84.3 °F (NTP, 1992);-64.6 °C;-64.6 °C;-64 °C;-83°F;-83°F

Flash Point

120 °F (NTP, 1992);84 °F (29 °C) (closed cup);48.9 °C, open cup;36 °C c.c.;103°F;103°F

Density

0.899 at 68 °F (USCG, 1999);0.8898 g/cu cm at 20 °C;Relative density (water = 1): 0.90;0.89;0.89

Solubility

less than 1 mg/mL at 68° F (NTP, 1992);0.02 M;Sol in ethanol, ethyl ether, acetone; slightly soluble in carbon tetrachloride;0.14 g/100 mL water at 20 °C; 9.12 g/100 mL at 40 °C;In water, 2,000 mg/L 23 °C;Solubility in water, g/100ml: 0.14;0.1%

Color/Form

Colorless liquid;Water-white monomer;Clear, colorless liquid [Note: Highly reactive; may contain an inhibitor to prevent spontaneous polymerization].

Complexity

97.1

Covalently-Bonded Unit Count

EC Number

205-480-7;618-366-0

Exact Mass

128.08373g/mol

Formal Charge

Heat of Vaporization

8.11 kcal/mol

Heavy Atom Count

ICSC Number

0400

Log P

2.36 (LogP);log Kow = 2.36;2.38

MeSH Entry Terms

acrylic acid butyl ester;butyl acrylate;butyl-(2,3-14C)-acrylate;n-butyl acrylate

Monoisotopic Mass

128.08373g/mol

NSC Number

5163

Odor

Sharp, fragrant;Sharp, biting characteristic odor;Strong, fruity odor

Other Experimental

Specific heat: 0.467 cal/g/deg C at -60 °C;BP: 138 °C at 760 mm Hg; 84-86 °C at 101 mm Hg; 59 °C at 25 mm Hg; 39 °C at 10 mm Hg; 35 °C at 8 mm Hg;Solubility of water in n-butyl acrylate at 20 °C: 0.8 mL/100 g;Specific gravity: 0.8986 at 20 °C/4 °C; 0.9110 at 15 °C/4 °C; 0.9117 at 12 °C/4 °C; 0.9202 at 0 °C/4 °C;Conversion factors: 5.23 mg/cu m = 1 ppm;Forms a slowly dissolving surface slick in water;Wt/gal 7.5 lb at 20 °C;Heat of evaporation: 192 J/g; Specific heat: 1.92 J/g-K;React readily with electrophilic, free-radical, and nucleophilic agent /Acrylic acid & esters/;Polymerizes readily on heating;Elastic, tacky substance. Brittle temp -45 °C /Polymer/;Henry's Law constant = 4.6X10-4 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 1.4X10-11 cu cm/molec-sec at 25 °C (est)

Refractive Index

Index of refraction: 1.4185 at 20 °C/D

Rotatable Bond Count

RTECS Number

UD3150000

UNII

705NM8U35V

UN Number

2348;2348;2348;2348

Vapor Density

4.42 (NTP, 1992) (Relative to Air);4.42 (Air = 1);Relative vapor density (air = 1): 4.42;4.42

Vapor Pressure