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  • Bis(triisopropylcyclopentadienyl)barium tetrahydrofuran adduct

  • Bis(triisopropylcyclopentadienyl)barium tetrahydrofuran adduct

    Catalog Number
    ACMA00016295
    Product Name
    Bis(triisopropylcyclopentadienyl)barium tetrahydrofuran adduct
    Category
    Vapor Deposition Precursors
    Synonyms
    Bis(1,2,4-triisopropylcyclopentadienyl)barium,Bis[1,2,4-tris(1-methylethyl)-2,4-cyclopentadien-1-yl]barium
    Molecular Formula
    [Ba(C5(C3H7)3H2)2] ⋅ 2(C4H8O)
    Canonical SMILES
    CC(C)[C]1[C][C](C(C)C)[C][C]1C(C)C.CC(C)[C]2[C][C](C(C)C)[C][C]2C(C)C.[Ba].C3CCOC3.C4CCOC4
    InChI
    1S/2C14H23.2C4H8O.Ba.2H/c2*1-9(2)12-7-13(10(3)4)14(8-12)11(5)6;2*1-2-4-5-3-1;;;/h2*7-11H,1-6H3;2*1-4H2;;;,XPFYNIUESMDERR-UHFFFAOYSA-N
    InChI Key
    XPFYNIUESMDERR-UHFFFAOYSA-N
    Melting Point
    284-289 °C
    Application
    Cyclopentadienyl compounds of Barium are very commonly used ALD/CVD precursors for depositing Barium containing thin films; example BaTiO3; BaZrO3 films. Cyclopentadienyl groups form weaker bonds with Barium, but have stronger bonds within the ligand thus preventing carbon contamination of the films. Cyclopentadienyl precursors of barium sublime under reduced pressures, with tetrahydrofuran adducts showing volatility also under atmospheric pressure. The tetrahydrofuran adducts loose the coordinated THF when evaporated. Complexes with bulky cyclopentadienyl ligands are more thermally stable and volatile.Barium containing thin films finds applications as host lattices for luminescent materials, high temperature superconductors, high permittivity dielectrics and ferroelectrics.
    Storage
    room temp
    Assay
    0.98
    Form
    powder
    Packaging
    1 g in glass bottle
    If you have any other questions or need other size, please get a quote.
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