CAS 53199-31-8 Bis(tri-tert-butylphosphine)palladium(0)

NAVIGATION

Bis(tri-tert-butylphosphine)palladium(0)

PRICE INQUIRY

Catalog Number

ACM53199318

CAS Number

53199-31-8

Product Name

Bis(tri-tert-butylphosphine)palladium(0)

Structure

Category

Polymerization Reagents

Synonyms

palladium,tritert-butylphosphane;Pd(t-Bu3P)2;

Description

Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes.

IUPAC Name

palladium;tritert-butylphosphane;

Molecular Weight

511.064g/mol

Molecular Formula

C24H54P2Pd

Canonical SMILES

CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd];

InChI

InChI=1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;;

InChI Key

MXQOYLRVSVOCQT-UHFFFAOYSA-N;

Melting Point

>300ºC

Flash Point

94.6ºC

Appearance

Off white crystalline solid

Application

Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.

A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.

Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.

Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.

Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.

Cross-coupling of silanolates and halides.

Elimination/isomerization of enol triflates derived from β-ketoesters.

Storage

Freezer

Complexity

128

Covalently-Bonded Unit Count

Exact Mass

510.274g/mol

Heavy Atom Count

Log P

9.72760

MDL Number

MFCD03094580