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Bis(acetonitrile)palladium(II) Dichloride

Catalog NumberACM14592564

CAS Number14592-56-4

CategorySalt

Bis(acetonitrile)palladium(II) Dichloride
Synonyms
Palladium(II) chloride diacetonitrile complex
IUPAC Name
acetonitrile;palladium(2+);dichloride
Molecular Weight
259.43
Molecular Formula
C4H6Cl2N2Pd
Canonical SMILES
CC#N.CC#N.[Cl-].[Cl-].[Pd+2]
InChI Key
RBYGDVHOECIAFC-UHFFFAOYSA-L
Boiling Point
63.5ºC at 760 mmHg
Flash Point
5.6ºC
Purity
99%,Pd >41
Appearance
orange powder
Application
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.

Catalyst for the aza-Michael reaction of carbamates with enones.

Catalyst for the rearrangement of allylic imidates to allylic amides.

Catalyst for the Nazarov cyclization of α-alkoxy dienones.

Catalyst for the diamination of conjugated dienes.

Three component Michael addition, cyclization, cross-coupling reaction.

C-H activation of indoles.

Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.
Storage
Room temperature.
Exact Mass
257.89400
Hazard Statements
H301-H311-H331
MDL Number
MFCD00013122
Safety Description
Danger
Stability
Stable under normal temperatures and pressures.
UN Number
UN 3077 9 / PGIII
WGK Germany
3
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